Researcher Database
HARAGUCHI Yuya
| ■Faculty | Institute of Engineering Division of Advanced Applied Physics | |||
| ■Position | Assistant Professor | |||
Last Updated :2023/11/06
Profile Information
Profile
I am developing new transition metal compounds with unique electronic and magnetic properties by extending the materials search space to metastable phases.
Activity information
Name and contact details
Name
ハラグチ ユウヤ, 原口 祐哉, HARAGUCHI YuyaYear of birth
1989E-mail
chiyuya3
go.tuat.ac.jp
Affiliation / Position
Institute of Engineering Division of Advanced Applied Physics, Assistant Professor
Other affiliation
Research History
大学院理学研究科
日本学術振興会特別研究員
From 01 Apr. 2016, To 31 Mar. 2017
物性研究所
特任研究員
From 01 Apr. 2017, To 28 Feb. 2019
工学研究科
助教
From 01 Mar. 2019
Education
- 京都大学
理学部
To 22 Mar. 2012, graduated - 京都大学
理学研究科
化学専攻
To 22 Mar. 2014, completed, master course - Kyoto University
Graduate School of Science
Department of Chemistry
To 20 Mar. 2017, completed, doctor course
Degree
Research Areas
- Natural Science, Magnetism, superconductivity and strongly correlated systems
- Nanotechnology/Materials, Inorganic/coordination chemistry
Research Interests
- Solid state chemistry
- Magnetism
- Condensed matter physics
- Quantum Materials
- Strongly correlated electron system
Subject of research
Teaching Experience
Grants-in-Aid for Scientific Research
- 若手研究
速度論的結晶場エンジニアリングで拓く新奇スピン軌道結合量子相
From 2022, To 2024 - 学術変革領域研究(A)（公募研究）
分子アニオン化合物を前駆体とする固相メタセシスの開拓と超セラミックス量子物質創製 - 若手研究
低温複分解を用いたキタエフ型磁性体のスピン軌道結合効果の制御と異常物性探索
From 2019, To 2022
Papers
- Magnetic ordering in the Jeff = 0 nickelate NiRh2O4 prepared via a solid-state metathesis
Y. Haraguchi, Daisuke Nishio-Hamane, and H. Aruga Katori
Physical Review Materials
American Physical Society
30 Aug. 2023, Research paper (scientific journal), joint, 7, 8, DOI(公開)(r-map), 084413-1, 084413-7 - Magnetic-field-induced valence change in Eu ( Co 1 − x Ni x ) 2 P 2 up to 60 T
Raito Nakamura, Azumi Ishita, Jin Nakamura, Hiroto Ohta, Yuya Haraguchi, Hiroko Aruga Katori, Hajime Ishikawa, Akira Matsuo, Koichi Kindo, Minoru Nohara, and Akihiko Ikeda
Physical Review B
American Physical Society
05 Jun. 2023, Research paper (scientific journal), joint, 107, 15, DOI(公開)(r-map), 235110-1, 235110-7 - Monoclinic Distortion in Hyperhoneycomb Kitaev Material β-ZnIrO3 Revealed by Improved Sample Quality
Yuya Haraguchi and Hiroko Aruga Katori
Chemistry Letters
The Chemical Society of Japan
05 May 2023, Research paper (scientific journal), joint, 52, 5, DOI(公開)(r-map), 404, 407 - Perfect kagome-lattice antiferromagnets with Jeff = 1/2: The Co2+-analogs of copper minerals volborthite and vesignieite
Y. Haraguchi, T. Ohnoda, A. Matsuo, K. Kindo, and H. Aruga Katori
Physical Review B
AMER PHYSICAL SOC
We report the synthesis, crystal structure, and magnetic properties of Co2+ kagome magnets Co3V2O7(OH)(2)middot2H(2)O and BaCo3(VO4)(2)(OH)(2), which can be recognized as Co analogs of the intensively researched quantum kagome magnet volborthite Cu3V2O7(OH)(2)middot2H(2)O and vesignieite BaCu3(VO4)(2)(OH)(2). For each compound, the ground state is seemingly A-type antiferromagnetic order. At low temperatures, applying a magnetic field causes a metamagneticlike transition described by the transition in which antiferromagnetically aligned canted moments change to ferromagnetically aligned ones. These ground and field-induced states include a canted ferromagnetic component perpendicular to the kagome planes favored by Dzyaloshinskii-Moriya interactions. These magnetic properties are well characterized by the J(eff) = 1/2 physics. Our findings will be a step toward clarifying the J(eff )= 1/2 kagome physics, which has not been thoroughly studied experimentally or theoretically.
19 Dec. 2022, Research paper (scientific journal), joint, 106, 21, 2469-9950, DOI(公開)(r-map), 214421 - 低温イオン交換を用いた新しいキタエフ物質の開発―固体化学の立場から見えてきたキタエフスピン液体の実現指針―
原口祐哉・香取浩子・道岡千城・植田浩明・吉村一良
固体物理
株式会社 アグネ技術センター
22 Nov. 2022, (MISC) Introduction and explanation (commerce magazine), joint, 57, 681, 745, 756 - Honeycomb lattice iridate on the verge of Mott-collapse
Yuya Haraguchi, and Hiroko Aruga Katori
JOURNAL OF PHYSICS-CONDENSED MATTER
IOP Publishing Ltd
A new honeycomb lattice iridate (La,Na)IrO3 (approximate to LaNaIr2O6) is successfully synthesized from the spin-orbit coupled Mott insulator Na2IrO3 by replacing the interlayer Na+ ions with La3+ ions. (La,Na)IrO3 shows a finite Sommerfeld term in heat capacity and a -lnT dependence of resistivity, indicating a realization of a metallic state driven by a Mott collapse. Furthermore, crystal structure analysis reveals the formation of Ir zig-zag chains with metal-metal bonding, increasing kinetic energy resulting in the Mott collapse. This observation would be due to a Mott collapse induced in a J (eff) = 1/2 spin-orbit coupling Mott insulator with an Ir honeycomb lattice by topochemical control of the ionic configuration.
16 Nov. 2022, Research paper (scientific journal), joint, 34, 46, 0953-8984, DOI(公開)(r-map), 465602-1, 465602-7 - Improvement of optical transmittance of SiO2 surface by femtosecond-laser-induced homogeneous nanostructure formation
Minami Edakubo, Lukas Janos Richter, Yuya Haraguchi, Hiroko Aruga-Katori, J?rgen Ihlemann, and Godai Miyaji
Optical Materials Express
Optica Publishing Group
It has been reported that periodic nanostructures with a period size of 200-330 nm can be formed on silicon suboxide (SiOx, x approximate to 1) with 800-nm, 100-fs laser pulses at a fluence much smaller than that needed for nanostructuring on glasses such as fused silica and borosilicate glass. We demonstrated that a homogeneous SiO2 nanostructure with a period of -240 nm can be produced using a two-step ablation process and heat treatment in air at 1000 degrees C for 144 hours. Optical microscopic images of the nanostructured surface illuminated by non-polarized visible light show that the transmittance increases as the reflectivity decreases.(c) 2022 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement
01 Oct. 2022, Research paper (scientific journal), joint, 12, 10, 2159-3930, DOI(公開)(r-map), 3982, 3989 - Observation of Topological Flat Bands in the Kagome Semiconductor Nb3Cl8
Zhenyu Sun, Hui Zhou, Cuixiang Wang, Shiv Kumar, Daiyu Geng, Shaosheng Yue, Xin Han, Yuya Haraguchi, Kenya Shimada, Peng Cheng, Lan Chen, Youguo Shi, Kehui Wu, Sheng Meng, Baojie Feng
Nano Letters
American Chemical Society
The destructive interference of wavefunctions in a kagome lattice can give rise to topological flat bands (TFBs) with a highly degenerate state of electrons. Recently, TFBs have been observed in several kagome metals, including Fe3Sn2, FeSn, CoSn, and YMn6Sn6. Nonetheless, kagome materials that are both exfoliable and semiconducting are lacking, which seriously hinders their device applications. Herein, we show that Nb3Cl8, which hosts a breathing kagome lattice, is gapped out because of the absence of inversion symmetry, while the TFBs survive because of the protection of the mirror reflection symmetry. By angle-resolved photoemission spectroscopy measurements and first-principles calculations, we directly observe the TFBs and a moderate band gap in Nb3Cl8. By mechanical exfoliation, we successfully obtain monolayer Nb3Cl8, which is stable under ambient conditions. In addition, our calculations show that monolayer Nb3Cl8 has a magnetic ground state, thus providing opportunities to study the interplay among geometry, topology, and magnetism.
08 Jun. 2022, Research paper (scientific journal), joint, 22, 11, 1530-6984, DOI(公開)(r-map), 4596, 4602 - Sinusoidal Magnetic Structure of Andalusite-type AlxFe2-xGeO5 with x = 0.09 and 0.15
Kazuo Kakimoto, Hiroto Ohta, Yuya Haraguchi, Masato Hagihala, Shuki Torii, Takashi Kamiyama, and Hiroko Aruga Katori
Journal of the Physical Society of Japan
Physical Society of Japan
Neutron diffraction experiments on polycrystalline andalusite-type AlxFe2-xGeO5 with x = 0.09 and 0.15 were performed. The magnetic Bragg peaks with the propagation vectors of kx=0.09 = (0, 0.150(1), 0) for the sample with x = 0.09 and kx=0.15 = (0, 0.141(1), 0) for the sample with x = 0.15 were observed, which means that an incommensurate magnetic order was realized for each sample. The calculation of the magnetic structure factors by the Pawley method and the analysis of the irreducible representations revealed that both samples have a magnetic structure in which the magnetic moments rotate in the crystallographic ab-plane with sinusoidal modulation along the b-axis. By the Luttinger-Tisza method, we determined the sign of the nearest-neighbor exchange interaction constants that reproduce the magnetic structures obtained by the irreducible representation analysis.
15 May 2022, Research paper (scientific journal), joint, 91, 5, 0031-9015, DOI(公開)(r-map), 054707 - Magnetism of AlxFe2-xGeO5 with Andalusite Structure
Kazuo Kakimoto, Saki Takada, Hiroto Ohta, Yuya Haraguchi, Masato Hagihala, Shuki Torii, Takashi Kamiyama, Hiroyuki Mitamura, Masashi Tokunaga, Atsushi Hatakeyama, and Hiroko Aruga Katori
Journal of the Physical Society of Japan
The Physical Society of Japan
The magnetism of AlxFe2-xGeO5 from x = 0.09 to 0.91 with the andalusite structure was examined. AlxFe2-xGeO5 at low temperatures was found to show a weak ferromagnet-like behavior for x 0.3 and a spin glass behavior for x 0.3. The small spontaneous magnetization observed in the weak ferromagnet-like samples may be caused by the existence of Dzyaloshinsky-Moriya interaction and the difference in the magnitudes of the magnetic moments of Fe3+ in the octahedral and trigonal bipyramidal sites. The appearance of the spin glass behavior implies that the dilution of Fe ions by Al ions in AlxFe2-xGeO5 causes the competition between ferromagnetic and antiferromagnetic interactions. The x dependence of the site occupancy of Fe ions suggests that Fe2GeO5 with the andalusite structure cannot be synthesized.
15 May 2022, Research paper (scientific journal), joint, 91, 5, 0031-9015, DOI(公開)(r-map), 054704-1, 054704-7 - Formation of the metastable iron(III) germanate Fe2GeO5 through kinetic control of the oxidative reaction
K. Kakimoto, Y. Ohki, S. Takada, Y. Haraguchi, A. Yamamoto, and H. Aruga Katori
Chemistry Letters
The Chemical Society of Japan
Synthesis of complex oxides requires high temperatures to overcome barriers due to the diffusion of solids. Therefore, the most stable polymorphs are obtained in general reactions. However, it is necessary to design kinetic reactions with low initial energy barriers and control the reaction path and products to synthesize novel and metastable oxides. We report the synthesis of a metastable Fe2GeO5 with a kyanite-type structure via kinetic control of oxidative reaction in Fe2GeO4. It is also found that Fe2GeO5 was not synthesized at all by the conventional method, high-pressure synthesis method, or coprecipitation method. Our result indicates that kinetic control of the oxidative reaction is a promising method for synthesizing metastable materials.
Apr. 2022, Research paper (scientific journal), joint, 51, 4, 0366-7022, DOI(公開)(r-map), 451, 454 - Magnetic properties of Eu(Co1-xNix)2P2
Raito Nakamura, Hiroto Ohta, Yoshio Kobayashi , Yuya Haraguchi, Hiroko Aruga Katori, and Jin Nakamura
Journal of the Physical Society of Japan
Physical Society of Japan
Solid solution 122-type compounds, Eu(Co1-xNix)(2)P-2, were investigated using crystallographic, magnetic, and Eu-151 Mossbauer effect measurements. A discontinuous isostructural phase transition from the uncollapsed tetragonal (ucT) to collapsed tetragonal (cT) structure was observed around x = 0.3. In the ucT region, Eu was divalent and showed helical magnetism of the Eu sublattice as well as at x = 0. However, in the cT region, Eu had an intermediate valence (+2.2 at 300 K) and showed paramagnetic behavior. The temperature dependence of the Eu valence was in good agreement with the Inter-Configurational Fluctuation (ICF) model. The Eu sublattice lost its magnetic order, but the Co/Ni sublattice exhibited itinerant ferromagnetism around 150 K. In addition, the net magnetization was lost due to the antiferromagnetic-like reorientation of the Co/Ni spins below 70 K. This magnetic structure was not observed in other 122-compounds and was a novel magnetic phase.
15 Feb. 2022, Research paper (scientific journal), joint, 91, 2, 0031-9015, DOI(公開)(r-map), 024701 - Spin-glass transition in the spin-orbit-entangled Jeff = 0 Mott insulating double-perovskite ruthenate
Hayato Yatsuzuka, Yuya Haraguchi, Akira Matsuo, Koichi Kindo & Hiroko Aruga Katori
Scientific Reports
Nature Portfolio
We have successfully synthesized new Ru4+ double perovskite oxides SrLaInRuO6 and SrLaGaRuO6, which are expected to be a spin-orbit coupled J(eff) = 0 Mott insulating ground state. Their magnetic susceptibility is much significant than that expected for a single Ru4+ ion for which exchange coupling with other ions is negligible. Their isothermal magnetization process suggests that there are about 20 percent isolated spins. These origins would be the Ru3+/Ru5+ magnetic defects, while the regular Ru4+ sites remain nonmagnetic. Moreover, SrLaGaRuO6 shows a spin-glass-like magnetic transition at low temperatures, probably caused by isolated spins. The observed spin-glass can be interpreted by the analogy of a dilute magnetic alloy, which can be seen as a precursor to the mobile J(eff) = 1 exciton as a dispersive mode as predicted.
14 Feb. 2022, Research paper (scientific journal), joint, 12, 1, 2045-2322, DOI(公開)(r-map), 2429 - Quantum paramagnetism in the hyperhoneycomb Kitaev magnet beta-ZnIrO3
Yuya Haraguchi, Arika Matsuo, Koichi Kindo, Hiroko Aruga Katori
Physical Review Materials
American Physical Society
A polycrystalline sample of the hyperhoneycomb iridate beta-ZnIrO3 was synthesized via a topochemical reaction, and its structural, magnetic, and thermodynamic properties were investigated. The magnetization and heat capacity data show the absence of long-range magnetic order at least down to 2 K. A positive Curie-Weiss temperature theta(w) similar to 45 K probed by the temperature dependence of magnetic susceptibility indicates that a Kitaev interaction is dominant. These observations suggest that a quantum spin liquid may have been realized. Furthermore, the observation of linear temperature-dependent contribution to the heat capacity with no magnetic field effect evidences gapless excitation. These facts are surprisingly contrary to the chemical disorder evidenced by the crystallographic analysis. By discussing the differences in the size effect of Z(2) fluxes in two-and three-dimensional Kitaev magnets, we propose that there is a hidden mechanism to protect the quantum spin liquid state from chemical disorder.
07 Feb. 2022, Research paper (scientific journal), joint, 6, 2, 2475-9953, DOI(公開)(r-map), L021401-1, L021401-6 - Quantum antiferromagnet bluebellite comprising a maple-leaf lattice made of spin-1/2 Cu2+ ions
Haraguchi, Yuya; Matsuo, Akira; Kindo, Koichi; Hiroi, Zenji
PHYSICAL REVIEW B
AMER PHYSICAL SOC
Spin-1/2 maple-leaf lattice antiferromagnets are expected to show interesting phenomena originating from frustration effects and quantum fluctuations. We report the hydrothermal synthesis of a powder sample of bluebellite Cu6IO3(OH)10Cl as a first potential candidate. Magnetization and heat capacity measurements reveal moderate frustration with a Curie-Weiss temperature of -35 K, and a magnetic transition at TN = 17 K. Surprisingly, the magnetic susceptibility and heat capacity above TN are well reproduced by the Bonner-Fisher model, which suggests that a one-dimensional spin correlation with a magnetic interaction of 25 K occurs in the apparently two-dimensional lattice. This emergent one-dimensionality cannot be explained by orbital ordering or dimensional reduction due to geometrical frustration. We believe that there is an unknown mechanism to cause one-dimensionality in the spin-1/2 maple-leaf lattice antiferromagnet.
29 Nov. 2021, Research paper (scientific journal), joint, 104, 17, 2469-9950, DOI(公開)(r-map), 174439-1, 174439-6 - Metallic state in the vicinity of molecular orbital crystallization in the d1 thiospinel ZnTi2S4 prepared via a reductive ion-exchange reaction
Haraguchi, Yuya; Arikai, Hiroki; Katori, Hiroko Aruga
JOURNAL OF PHYSICS-CONDENSED MATTER
IOP PUBLISHING LTD
A novel Ti3+-based thiospinel ZnTi2S4 is successfully synthesized via a low-temperature ion-exchange reaction. ZnTi2S4 shows a signature of metallic ground state evidenced by a contribution of conduction electrons in the heat capacity and Pauli-like paramagnetic susceptibility. These observations contrast to the electronic state of similar Ti3+-based spinel MgTi2O4 exhibiting the metal-insulator transition associated with a molecular orbital crystallization (MOC). Furthermore, the magnetic susceptibility of ZnTi2S4 shows a pseudogap-like behavior indicated by a vast peak in the magnetic susceptibility around 110 K, likely originating from the MOC fluctuation. The origin of the difference in the electronic states of MgTi2O4 and ZnTi2S4 would be due to the different magnitude of overlap between Ti 3d and p orbitals (O: 2p and S: 3p). The presence of a MOC state in the close vicinity of insulator-metal transition may suggest the importance of itinerancy in a MOC.
29 Sep. 2021, Research paper (scientific journal), joint, 33, 39, 0953-8984, DOI(公開)(r-map), 395603 - 4d3 Ru5+ triangular lattice antiferromagnets: Layered rock-salt beta-Li3Mg2RuO6 and ion-exchanged delafossite Ag3Mg2RuO6
Haraguchi, Yuya; Kakimoto, Kazuo; Katori, Hiroko Aruga
JOURNAL OF SOLID STATE CHEMISTRY
ACADEMIC PRESS INC ELSEVIER SCIENCE
Y The crystal structure and magnetic properties of Ru5+ triangular lattice antiferromagnets beta-Li3Mg2RuO6 and Ag3Mg2RuO6 are reported. We successfully synthesized a pseudohexagonal layered rock-salt type phase beta-Li3Mg2RuO6 with 2:1 ordering of Mg and Ru, which is a polymorph of an orthorhombic partial ordered rock-salt phase alpha-Li3Mg2RuO6. Shortening a calcinating time and adding excessive amounts of Li can prevent a polymorphic transformation from beta-Li3Mg2RuO6 to alpha-Li3Mg2RuO6. An ordered delafossite compound Ag3Mg2RuO6 has been obtained by topochemical molten salt ionic exchange reaction to beta-Li3Mg2RuO6. In beta-Li3Mg2RuO6 and Ag3Mg2RuO6, multiple superexchange pathways Ru5+-O2--O2--Ru5+ leads to large antiferromagnetic interactions of theta(W) = -113.9 and -108.1 K, respectively, despite a long distance between the magnetic Ru5+ ions. In addition, beta-Li3Mg2RuO6 and Ag3Mg2RuO6 exhibit antiferromagnetic orderings with a trace of spin glasslike contribution at T-N = 13 and 24 K, respectively, which is evidenced by the heat capacity measurement. While beta-Li3Mg2RuO6 exhibits a magnetic behavior that follows the Curie-Weiss curve up to just above T-N, Ag3Mg2RuO6 exhibits a magnetic behavior that deviates from the Curie-Weiss curve below 100 K, which is considerably higher than T-N. The different magnetic behaviors suggest a difference in magnetic dimensionality, indicating that the difference in the coordination environment around interlayer between Li+ and Ag+ ions gives rise to considerably different interlayer superexchange pathways in both systems.
Jul. 2021, Research paper (scientific journal), joint, 299, 0022-4596, DOI(公開)(r-map), 122171-1, 122171-6 - Strong antiferromagnetic interaction owing to a large trigonal distortion in the spin-orbit-coupled honeycomb lattice iridate CdIrO3
Yuya Haraguchi, and Hiroko Aruga Katori
Physical Review Materials
American Physical Society.
03 Apr. 2020, Research paper (scientific journal), joint, 4, 4, DOI(公開)(r-map), 044401-1, 044401-5 - Frustrated magnetism in the J1-J2 honeycomb lattice compounds MgMnO3 and ZnMnO3 synthesized via a metathesis reaction
Haraguchi, Yuya; Nawa, Kazuhiro; Michioka, Chishiro; Ueda, Hiroaki; Matsuo, Akira; Kindo, Koichi; Avdeev, Maxim; Sato, Taku J.; Yoshimura, Kazuyoshi
PHYSICAL REVIEW MATERIALS
AMER PHYSICAL SOC
We investigated the magnetic properties of the ilmenite-type manganates MgMnO3 and ZnMnO3, both of which are composed of a honeycomb lattice of magnetic Mn4+ ions. Both compounds show antiferromagnetic order with weak ferromagnetic moments. In particular, MgMnO3 exhibits a magnetization reversal behavior which can be described by the N-type ferrimagnetism in the Neel's classification. The relationship between the magnetic properties and the crystal and magnetic structures probed by the neutron diffraction experiments indicates that the two honeycomb lattice magnets have different J(1)-J(2) parameter sets, placing them in the distinct regions in the phase diagram; both nearest neighbor (NN) and next nearest neighbor (NNN) exchange interactions are antiferromagnetic in MgMnO3, while NN and NNN interactions become ferromagnetic and antiferromagnet, respectively, in ZnMnO3.
17 Dec. 2019, Research paper (scientific journal), joint, 3, 12, 2475-9953, DOI(公開)(r-map) - Frustrated magnetism of the maple-leaf-lattice antiferromagnet MgMn3O7 3H2O
Haraguchi, Yuya; Matsuo, Akira; Kindo, Koichi; Hiroi, Zenji
PHYSICAL REVIEW B
AMER PHYSICAL SOC
We present the novel hydrated layered manganate MgMn3O7 center dot 3H(2)O as a maple-leaf-lattice (MLL) antiferromagnet candidate. The MLL is obtained by regularly depleting 1/7 of the lattice points from a triangular lattice so that the magnetic connectivity z = 5 and is thus intermediately frustrated between the triangular (z = 6) and kagome (z = 4) lattices. In MgMn3O7 center dot 3H(2)O, the Mn4+ ions carrying Heisenberg spin 3/2 form a regular MLL lattice in the quasi-two-dimensional structure. Magnetization and heat capacity measurements using a hydrothermally prepared powder sample reveal successive antiferromagnetic transitions at 5 and 15 K. A high-field magnetization curve up to 60 Tat 1.3 K exhibits a multistep plateaulike anomaly. We discuss the unique frustration of the MLL antiferromagnet in which the chiral degree of freedom may play an important role.
13 Aug. 2018, Research paper (scientific journal), joint, 98, 064412, 2469-9950, DOI(公開)(r-map) - Magnetic ordering with an XY-like anisotropy in the honeycomb lattice iridates ZnIrO3 and MgIrO3 synthesized via a metathesis reaction
Haraguchi, Yuya; Michioka, Chishiro; Matsuo, Akira; Kindo, Koichi; Ueda, Hiroaki; Yoshimura, Kazuyoshi
PHYSICAL REVIEW MATERIALS
AMER PHYSICAL SOC
We have successfully synthesized the novel antiferromagnets with Ir4+ honeycomb lattice ZnIrO3 and MgIrO3 and investigated their magnetic and thermodynamic properties. The two iridates are isomorphic but exhibit qualitatively different magnetic properties. ZnIrO3 shows antiferromagnetic ordering below 46.6 K, whereas MgIrO3 displays weak ferromagnetic behavior below 31.8 K, owing to formation of a canted antiferromagnetic ordering. The measurement of magnetic susceptibility with using an oriented powder sample revealed the presence of an XY-like magnetic anisotropy and a tilting magnetic structure which is possibly stabilized by the Kitaev interaction. Moreover, magnetization curves of ZnIrO3 and MgIrO3 up to 60 T show different behaviors, demonstrating that each magnetic ground state is different with each other. We discuss the difference in the ground state between ZnIrO3 and MgIrO3 from the viewpoint a magnetic model consisting of the Kitaev and Dzyaloshinskii-Moriya interactions with the spin-frustration effect on the honeycomb lattice.
18 May 2018, Research paper (scientific journal), joint, 2, 054411, 2475-9953, DOI(公開)(r-map) - Highly Spin-frustrated Magnetism in the Topochemically Prepared Triangular Lattice Cluster Magnets Na3A2(MoO4)2Mo3O8 (A = In, Sc)
Yuya Haraguchi, Chishiro Michioka, Hiroaki Ueda, and Kazuyoshi Yoshimura
Chemistry - A European Journal
Wiley VCH Verlag GmbH and Co
09 Oct. 2017, Research paper (scientific journal), joint, 23, DOI(公開)(r-map), 15879, 15883 - Magnetic-nonmagnetic Phase Transition with Interlayer Charge Disproportionation of Nb3 Trimers in the Cluster Compound Nb3Cl8
Yuya Haraguchi, Chishiro Michioka, Manabu Ishikawa, Yoshiaki Nakano, Hideki Yamochi, Hiroaki Ueda, and Kazuyoshi Yoshimura
Inorganic Chemistry
American Chemical Society
27 Feb. 2017, Research paper (scientific journal), joint, 56, 6, DOI(公開)(r-map), 3483, 3488 - Tetramer spin singlet instability in the fluorine-substituted pyrochlore superconducting system Cd2Re2O7-xFx
Yuya Haraguchi, Chishiro Michioka, Hiroaki Ueda, and Kazuyoshi Yoshimura
Journal of Physics: Condensed Matter
IOP Publishing Ltd
06 Jul. 2016, Research paper (scientific journal), joint, 28, 355602, DOI(公開)(r-map) - Spin-liquid behavior in the spin-frustrated Mo3 cluster magnet Li2ScMo3O8 in contrast to magnetic ordering in isomorphic Li2InMo3O8
Yuya Haraguchi, Chishiro Michioka, Masaki Imai, Hiroaki Ueda, and Kazuyoshi Yoshimura
Physical Review B
09 Jul. 2015, Research paper (scientific journal), joint, 92, 014409, DOI(公開)(r-map) - Unconventional multicritical point in the S = 1/2 Re2-cluster magnet La3Re2O10
Yuya Haraguchi, Chishiro Michioka, Hiroaki Ueda, and Kazuyoshi Yoshimura
Physical Review B
American Physical Society
05 Aug. 2014, Research paper (scientific journal), joint, 90, 064403, DOI(公開)(r-map)
Presentations
- 過剰アルカリ金属インターカレート系Mo3クラスターMott絶縁体における創発的三角格子磁性
日本物理学会2022年秋季大会
12 Sep. 2022, Oral presentation(general) - 新規キタエフ模型候補物質CaCo2TeO6の中性子回折
日本物理学会2022年秋季大会
12 Sep. 2022, Oral presentation(general) - 高スピンd7キタエフ磁性体CaCo2TeO6の磁気異方性評価
日本物理学会2022年秋季大会
13 Sep. 2022, Oral presentation(general) - 固体化学の立場から見えてきたキタエフ磁性体の開発指針
第32回日本MRS年次大会
06 Dec. 2022, Oral presentation(invited, special) - 低温固相メタセシスによって合成した四面体配位d8系スピン軌道結合J=0磁性候補物質NiRh2O4における磁気秩序の観測
日本物理学会2022年秋季大会
13 Sep. 2022, Oral presentation(general) - Frustrated magnetism in alkaline-intercalated Mo3O8-type compounds
29th International Conference on Low Temperature Physics
23 Aug. 2022, Poster presentation - Kitaev spin liquid signature in the hyperhoneycomb iridate
29th International Conference on Low Temperature Physics
22 Aug. 2022, Poster presentation - 新しいS = 1カゴメ格子ニッケル化合物の磁化プラトー
日本物理学会 第77回年次大会（2022年）
15 Mar. 2022, Oral presentation(general) - From rocksalt to ilmenite: a metathesis route for the synthesis of novel quantum materials
Pacifichem 2021
17 Dec. 2021, Oral presentation(general) - 中間原子価化合物Eu(Co1-xNix)2P2の151Euメスバウアー分光測定によるEu価数の研究
日本物理学会2021年秋季大会
23 Sep. 2021, Poster presentation - ハイパーハニカム格子を有するKitaev常磁性体β-ZnIrO3の磁気状態の再考および周辺物質の探索
日本物理学会2021年秋季大会
22 Sep. 2021, Oral presentation(general) - kyanite構造Fe2GeO5の磁性
日本物理学会2021年秋季大会
22 Sep. 2021, Oral presentation(general) - ハニカム格子系Jeff = 0スピン軌道結合磁性体候補物質CdRuO3
日本物理学会2021年秋季大会
21 Sep. 2021, Oral presentation(general) - 高スピンd7電子系Kitaev-Heisenberg模型カゴメ格子反強磁性体BaCo3(XO4)2(OH)2 (X = V, As)の合成と磁性
日本物理学会2021年秋季大会
21 Sep. 2021, Poster presentation - ハニカム格子を持つイリジウム酸化物のトポケミカル合成の最近の動向
日本物理学会2021年秋季大会
20 Sep. 2021, Poster presentation - 低温固相メタセシスによるサイトミクスチャーの無いスピネル酸化物MgCo2O4の合成
粉体粉末冶金協会2021年度春季大会
07 Jun. 2021, Oral presentation(general) - S=1/2二次元メイプルリーフ格子反磁性体Bluebelliteにおける創発的一次元磁性
日本物理学会第76回年次大会
15 Mar. 2021, Oral presentation(general) - 新しいKitaev-Heisenberg磁性体CaCo2TeO6における磁場誘起スピン液体の可能性
日本物理学会第76回年次大会
15 Mar. 2021, Oral presentation(general) - イルメナイト型ルテネイトMgRuO3におけるスピン軌道結合金属の可能性
日本物理学会第76回年次大会
13 Mar. 2021, Oral presentation(general) - Jeff = 0スピン軌道結合磁性候補物質SrLaGaRuO6におけるスピングラス転移
日本物理学会第76回年次大会
13 Mar. 2021, Oral presentation(general) - andalusite構造AlxFe2-xGeO5(x = 0.15, 0.2)の磁気構造研究
日本物理学会第76回年次大会
12 Mar. 2021, Oral presentation(general) - 中間原子価化合物Eu(Co1-xNix)2P2の構造と磁性
日本物理学会第76回年次大会
12 Mar. 2021, Oral presentation(general) - 低温合成による新しいキタエフ物質の探索
第135回フロンティア材料研究所講演会
21 Jan. 2021, Oral presentation(invited, special) - Search for novel Kitaev magnets by means of topochemical manipulation
第30回日本MRS年次大会
10 Dec. 2020, Oral presentation(invited, special) - トポケミカル安定化されたハニカム格子イリジウム酸化物の物性
日本物理学会2020年秋季大会
10 Sep. 2020, Oral presentation(general) - Relationship between the crystal structure and magnetism in spin-orbit coupled iridates with an ilmenite structure
日本物理学会第75回年次大会
17 Mar. 2020, Oral presentation(general) - 低温複分解反応を用いた新規キタエフ候補物質の探索
日本物理学会2019年秋季大会
10 Sep. 2019, Poster presentation - 新しいハイパーハニカム格子イリジウム酸化物の合成と物性
日本物理学会第74回年次大会
16 Mar. 2019, Oral presentation(general)